tempooxidation

由 A Hinzmann 著作 · 2020 · 被引用 14 次 — The TEMPO-catalyzed oxidation of alcohols to aldehydes has emerged to one of the most widely applied methodologies for such transformations.

A highly efficient and mild procedure for the oxidation of different types of alcohols uses TEMPO as catalyst, iodobenzene dichloride as stoichiometric oxidant, ...

The oxidation of TEMPO can be highly selective. It has been proven that secondary alcohols are more likely to be oxidized by TEMPO under an acidic environment.

2014年3月24日 — Reaction Mechanism. The N-oxoammonium cation produced by the oxidation of TEMPO works as the active oxidizing species.

由 A Isogai 著作 · 2022 · 被引用 18 次 — TEMPO-catalyzed oxidation is a unique method for converting plant celluloses to almost completely individualized cellulose microfibrils, which ...

The mechanism of TEMPO-mediated alcohol oxidation proceeds through an alkoxide adduct under basic conditions, or through a bimolecular hydride transfer under ...

由 MA Khansary 著作 · 2020 · 被引用 19 次 — In order to study the TEMPO-oxidation of cellulose molecules, we used Density Functional Theory (DFT) calculations and Flory-Huggins theory ...

由 G Pierre 著作 · 2017 · 被引用 147 次 — The oxidation of natural polysaccharides by TEMPO has become by now an “old chemical reaction” which led to numerous studies mainly conducted on ...

All TEMPO oxidations are exothermic and may present delayed exotherms. Compatibility of NaOCl with other reaction components must be considered. Toxicity and ...